# Investigation of Silver and Copper Doping on Antimony Sulfide Thin Films Obtained by Electrophoretic Deposition

https://mdr.nims.go.jp/datasets/05a03991-1f83-44e1-9edd-cfbd5a84e4c0

## File

- [J Phys Chem C 128 (2024) 18093-18101_Accepted manuscript.docx](https://mdr.nims.go.jp/filesets/7444ea56-80ee-4616-a715-a956d6dc9c66/download) ([Detail](https://mdr.nims.go.jp/filesets/7444ea56-80ee-4616-a715-a956d6dc9c66.md))

## Id

05a03991-1f83-44e1-9edd-cfbd5a84e4c0

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-12-25T00:21:30.921367Z

## Updated at

2025-10-23T23:30:26.887639Z

## Published at

2025-10-23T23:18:38.628631Z

## Doi

https://doi.org/10.48505/nims.5222

## First published url

https://doi.org/10.1021/acs.jpcc.4c04781

## Date published

2024-10-24

## Recorded date published

2024-10-24

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: Investigation of Silver and Copper Doping on Antimony Sulfide Thin Films
    Obtained by Electrophoretic Deposition
  title_type: original
  lang: en

## Description

- description: In this work, we demonstrate the production of pure and doped Sb2S3
    thin films by electrophoretic deposition. The consequences of silver and copper
    doping were evaluated by measuring the films’structural and optoelectrical properties.
    Sb2S3 nanoparticles (NPs) were first synthesized in ethylene glycol and stabilized
    with polyethylenimine. Doped NPs were obtained thanks to silver or copper precursors
    added during the synthesis process. Orthorhombic Sb2S3 and extra AgSbS2 and CuSbS2
    phases were identified by XRD after thermal treatment at 300 °C under vacuum.
    Metallic Sb impurities were also found for thermal treatment under 275 °C. UV−vis−NIR
    spectroscopy highlighted the optical properties of amorphous and crystalline thin
    films as well as the variation of optical band gaps by doping. Photocurrent measurement
    showed an increase in conductivity for doped thin films. Adding silver or copper
    also brought a slower recombination of electron−hole pairs after switching the
    light off.
  description_type: abstract
  lang: und

## Creator

- name: Clement Lebastard
  role: author
  orcid: https://orcid.org/0000-0002-4302-3603
- name: Christopher L. Hassam
  role: author
- name: Tohru Suzuki
  role: author
  orcid: https://orcid.org/0000-0001-9458-6863
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Tetsuo Uchikoshi
  role: author
  orcid: https://orcid.org/0000-0003-3847-4781
  organization: National Institute for Materials Science
  ror: https://ror.org/026v1ze26
- name: Yohann Thimont
  role: author
- name: David Berthebaud
  role: author
  orcid: https://orcid.org/0000-0002-2892-2125

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: Electrophoretic deposition
  schema: not_defined
- subject: thin films
  schema: not_defined
- subject: chalcogenides
  schema: not_defined
- subject: coating materials
  schema: not_defined

## Rights

- description: This document is the Accepted Manuscript version of a Published Work
    that appeared in final form in Investigation of Silver and Copper Doping on Antimony
    Sulfide Thin Films Obtained by Electrophoretic Deposition, copyright © 2024 American
    Chemical Society after peer review and technical editing by the publisher. To
    access the final edited and published work see https://doi.org/10.1021/acs.jpcc.4c04781
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-10-24
end_date: 2025-10-24

## Journal

- title: The Journal of Physical Chemistry C
  issn: '19327447'
  volume: '128'
  issue: '42'
  start_page: 18093
  end_page: 18101

## Conference



## Related item



## Funding

- identifier: JSPS PE21752
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



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## Fileset

- id: 7444ea56-80ee-4616-a715-a956d6dc9c66
  filename: J Phys Chem C 128 (2024) 18093-18101_Accepted manuscript.docx
  content_type: application/vnd.openxmlformats-officedocument.wordprocessingml.document
  size: 1740097
  md5: c6581d10e591ff0def72d582d3c43fa2

## Thumbnail

fileset_id: 7444ea56-80ee-4616-a715-a956d6dc9c66
filename: J Phys Chem C 128 (2024) 18093-18101_Accepted manuscript.docx