Article Supra-ceramics: A molecule-driven frontier of inorganic materials

Kazuhiko Maeda (Department of Chemistry, School of Science, Institute of Science Tokyo) ; Teruki Motohashi (Department of Applied Chemistry, Faculty of Chemistry and Biochemistry, Kanagawa University) ; Ryo Ohtani (Department of Chemistry, Faculty of Science, Kyushu University) ; Kunihisa Sugimoto (Department of Chemistry, Faculty of Science and Engineering, Kindai University) ; Yuta Tsuji (Faculty of Engineering Sciences, Kyushu University) ; Akihide Kuwabara (Nanostructures Research Laboratory, Japan Fine Ceramics Center) ; Satoshi Horike (Department of Chemistry, Graduate School of Science, Kyoto University)

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Kazuhiko Maeda, Teruki Motohashi, Ryo Ohtani, Kunihisa Sugimoto, Yuta Tsuji, Akihide Kuwabara, Satoshi Horike. Supra-ceramics: A molecule-driven frontier of inorganic materials. Science and Techonology of Advanced Materials. 2024, 25 (1), 2416384. https://doi.org/10.48505/nims.5349

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(abstract)

Discoveries and technological innovations over the past decade are transforming our understanding of the properties of ceramics, such as ‘hard’, ‘brittle’, and ‘homogeneous’. For example, inorganic crystals containing molecular anions exhibit excellent secondary battery characteristics, and the fusion of inorganic solids and molecules results in innovative catalytic functions and physical properties. Different from the conventional ceramics such as metal oxides that are formed by monatomic cations and anions, unique properties and functions can be expected in molecular-incorporated inorganic solids, due to the asymmetric and dynamic properties brought about by the constituent molecular units. We name the molecular-incorporated inorganic materials that produce innovative properties and functions as supra-ceramics. In this article, we describe various kinds of supra-ceramics from the viewpoint of synthesis, analysis and physical properties/functions for a wide range of applications.

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Keyword: metal complexes, organic-inorganic hybrids, perovskites, metalorganic frameworks, coordination polymers, batteries, solar cells, photocatalysis, proton conductors, CO2 conversion

Date published: 2024-12-31

Publisher: Taylor&Francis

Journal:

  • Science and Techonology of Advanced Materials (ISSN: 14686996) vol. 25 issue. 1 2416384

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Manuscript type: Author's version (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5349

First published URL: https://doi.org/10.1080/14686996.2024.2416384

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Updated at: 2025-02-28 16:30:14 +0900

Published on MDR: 2025-02-28 16:30:15 +0900

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