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Discoveries and technological innovations over the past decade are transforming our understanding of the properties of ceramics, such as ‘hard’, ‘brittle’, and ‘homogeneous’. For example, inorganic crystals containing molecular anions exhibit excellent secondary battery characteristics, and the fusion of inorganic solids and molecules results in innovative catalytic functions and physical properties. Different from the conventional ceramics such as metal oxides that are formed by monatomic cations and anions, unique properties and functions can be expected in molecular-incorporated inorganic solids, due to the asymmetric and dynamic properties brought about by the constituent molecular units. We name the molecular-incorporated inorganic materials that produce innovative properties and functions as supra-ceramics. In this article, we describe various kinds of supra-ceramics from the viewpoint of synthesis, analysis and physical properties/functions for a wide range of applications.

権利情報:

• Creative Commons BY Attribution 4.0 International
  

キーワード: metal complexes, organic-inorganic hybrids, perovskites, metalorganic frameworks, coordination polymers, batteries, solar cells, photocatalysis, proton conductors, CO2 conversion

刊行年月日: 2024-12-31

出版者: Taylor&Francis

掲載誌:

• Science and Technology of Advanced Materials (ISSN: 14686996) vol. 25 issue. 1 2416384

研究助成金:

原稿種別: 著者最終稿 (Accepted manuscript)

MDR DOI: https://doi.org/10.48505/nims.5349

公開URL: https://doi.org/10.1080/14686996.2024.2416384

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更新時刻: 2025-07-16 16:17:06 +0900

MDRでの公開時刻: 2025-02-28 16:30:15 +0900