# Layered Silicates Exhibiting MOF-Like Gate-Opening Behaviors in Liquid-Phase Adsorptions: Experimental and Theoretical Investigations

https://mdr.nims.go.jp/datasets/00023d44-2fa4-4a01-bdd7-27ad2ae9b82c

## File

- [24_ACS_AMI_51046_MDR.docx](https://mdr.nims.go.jp/filesets/c3777e2f-a928-4465-845e-b95bf45953df/download) ([Detail](https://mdr.nims.go.jp/filesets/c3777e2f-a928-4465-845e-b95bf45953df.md))

## Id

00023d44-2fa4-4a01-bdd7-27ad2ae9b82c

## Local identifier



## Visibility

open_to_public

## State

published

## Created at

2024-12-04T07:34:17.170402Z

## Updated at

2025-09-08T23:30:27.715440Z

## Published at

2025-09-08T23:17:52.307363Z

## Doi

https://doi.org/10.48505/nims.5095

## First published url

https://doi.org/10.1021/acsami.4c08845

## Date published

2024-09-25

## Recorded date published

2024-9-25

## Resource type

journal_article

## Manuscript type

accepted_manuscript

## Collection



## Title

- title: 'Layered Silicates Exhibiting MOF-Like Gate-Opening Behaviors in Liquid-Phase
    Adsorptions: Experimental and Theoretical Investigations'
  title_type: original
  lang: en

## Description

- description: Layered silicates, including clay minerals, can be used as liquidphase
    adsorbents in many important applications. However, because their twodimensional
    interlayer space is narrow and not entirely opened due to the presence of interlayer
    species, guest species are forced to penetrate while expanding the interlayer
    space, which limits their adsorption performances compared with microporous materials
    such as MOFs and zeolites. Herein, as reported for the adsorption of gaseous species
    on flexible MOFs, we report a layered silicate that exhibits gate-opening adsorption
    in liquid phases.
  description_type: abstract
  lang: und

## Creator

- name: Mohamed Esmat
  role: author
  orcid: https://orcid.org/0000-0003-1465-0955
- name: Hamza El-Hosainy
  role: author
  orcid: https://orcid.org/0000-0001-8244-4382
- name: Masaya Miyagawa
  role: author
  orcid: https://orcid.org/0000-0002-3141-9440
- name: Hiromitsu Takaba
  role: author
- name: Nao Tsunoji
  role: author
  orcid: https://orcid.org/0000-0003-4919-702X
- name: Shinsuke Ishihara
  role: author
  orcid: https://orcid.org/0000-0001-6854-6032
- name: Yusuke Ide
  role: author
  orcid: https://orcid.org/0000-0002-6901-6954

## Contact agent



## Publisher

organization: American Chemical Society (ACS)

## Managing organization



## Keyword

- subject: layered silicate
  schema: not_defined
- subject: microporous layered silicate
  schema: not_defined
- subject: MOF
  schema: not_defined
- subject: zeolite
  schema: not_defined
- subject: gate opening
  schema: not_defined
- subject: adsorption
  schema: not_defined

## Rights

- description: This document is the Accepted Manuscript version of a Published Work
    that appeared in final form in ACS Applied Materials & Interfaces, copyright ©
    2024 American Chemical Society after peer review and technical editing by the
    publisher. To access the final edited and published work see https://doi.org/10.1021/acsami.4c08845.
  identifier: http://rightsstatements.org/vocab/InC/1.0/

## Other identifier(s)



## Data origin

- data_origin_type: other

## Embargo

start_date: 2024-09-09
end_date: 2025-09-09

## Journal

- title: ACS Applied Materials & Interfaces
  issn: '19448244'
  volume: '16'
  issue: '38'
  start_page: 51046
  end_page: 51054

## Conference



## Related item



## Funding

- identifier: 21H02034
  funder_name: Japan Society for the Promotion of Science

## Instrument



## Instrument operator



## Instrument managing organization



## Measurement method



## Specimen



## Chemical composition



## Structure for specimen



## Structural feature for specimen



## Specific property for specimen



## Process for specimen treatment



## Computational method



## Energy level/transition state



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## Custom property



## Fileset

- id: c3777e2f-a928-4465-845e-b95bf45953df
  filename: 24_ACS_AMI_51046_MDR.docx
  content_type: application/vnd.openxmlformats-officedocument.wordprocessingml.document
  size: 2027465
  md5: 2adc066189ab607203c678effcc4a0fa

## Thumbnail

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filename: 24_ACS_AMI_51046_MDR.docx